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Boron cluster forms unique ring system

by Andy Extance, RSC last modified 01-25-10 05:44 AM Copyright 2010, RSC
Boron cluster forms unique ring system

B19- features a central 6-atom pentagon that shares two pi-electrons, surrounded by thirteen boron atoms that share 10 pi-electrons © Nature Chemistry

Clusters of nineteen boron atoms gather together in a ring structure unlike any other seen, with two planar Pi-bonded aromatic systems nestled inside one another.   

Lai-Sheng Wang at Brown University and Alexander Boldyrev at Utah State University in the US made the discovery: 'I was really excited when my postdoc, Wei Huang, first showed it to me,' Wang told Chemistry World. 'It's so beautiful, so circular.' 

The US chemists found that the lowest energy form of B19- boasts a pentagonal six-atom group sharing two Pi-electrons, surrounded by thirteen boron atoms sharing ten electrons. Although concentric Pi-systems have been seen in organic molecules, none have exactly this electronic configuration.  More...

http://www.rsc.org/chemistryworld/News/2010/January/24011001.asp

 

 

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